F51 Material Equivalent And Chemical Composition

Dec 16, 2025

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What is F51 Duplex Stainless Steel?

 

F51, most commonly known as UNS S31803 or 2205, is a duplex stainless steel. As a "duplex" alloy, its microstructure consists of a balanced, roughly 50/50 mix of ferrite and austenite phases.

 

What is F51 Duplex Stainless Steel

 

Initially standardized as UNS S31803, the alloy has evolved. Manufacturers often produce it at the upper end of the elemental ranges for enhanced performance, leading to the introduction of a tighter specification known as UNS S32205 (F60 in forging standards). S32205 is the modern, preferred specification for guaranteed high corrosion resistance.

 

F51 Material Equivalent

 

F51/2205 is recognized under numerous standard systems worldwide. The table below outlines its key equivalent grades.

 

Standard System

Equivalent Designation(s)

UNS (Unified Numbering System)

S31803, S32205

EN (European Standard)

1.4462

EN Chemical Name

X2CrNiMoN22-5-3

Common/Trade Names

2205, SAF 2205

Chinese Standard

00Cr22Ni5Mo3N

Forged Product Standard (ASTM A182)

F51, F60

 

ASTM A240 / A276 F51 Chemical Composition

 

Element

Weight % (S31803)

Carbon (C)

0.030 max

Chromium (Cr)

21.0 – 23.0

Nickel (Ni)

4.5 – 6.5

Molybdenum (Mo)

2.5 – 3.5

Nitrogen (N)

0.08 – 0.20

Manganese (Mn)

2.00 max

Silicon (Si)

1.00 max

Phosphorus (P)

0.030 max

Sulfur (S)

0.020 max

Iron (Fe)

Balance

 

Minimum Mechanical Properties

 

Property

Value (S31803 / S32205)

Tensile Strength

≥ 620 MPa (90 ksi)

Yield Strength (0.2%)

≥ 450 MPa (65 ksi)

Elongation in 50 mm

≥ 25 %

Hardness (Brinell)

≤ 290 HBW (typically 230–260)

Impact Toughness (Charpy V, -46 °C)

≥ 100 J average (common requirement)

 

F51 Material Advantages

 

F51 Material Advantages

 

Excellent Corrosion Resistance

 

Twice the pitting and crevice corrosion resistance of 316L in chloride environments.

 

Outstanding resistance to stress corrosion cracking (SCC) in sour (H₂S) and chloride-bearing media.

 

High Mechanical Strength

 

Approximately double the proof strength of austenitic grades → allows significant wall-thickness reduction and weight savings.

Cost Effectiveness

 

Lower nickel and molybdenum content than super duplex S32750/S32760 and 6Mo austenitics, yet delivers superior performance in most seawater and process applications.

 

Good Weldability and Fabricability

 

Can be welded with matching 2209 filler (ER2209 / E2209-17) or over-alloyed 2594 filler for optimum properties.

 

Solution annealing at 1020–1100°C followed by rapid water quenching restores phase balance.

 

Wide Temperature Range

 

Suitable from -50°C up to approximately 280°C without risk of 475°C embrittlement or sigma-phase formation in properly heat-treated material.

 

Available F51 Product Forms from Stock

 

Available F51 Product Forms from Stock

 

We maintain extensive inventory of F51/S32205 seamless and welded butt-weld fittings to ASME B16.9, MSS SP-43, and EN 10253:

 

Long & Short Pattern Stub Ends (Type A/B)

 

Elbows 45°/90°/180° LR & SR

 

Equal & Reducing Tees

 

Concentric / Eccentric Reducers

 

Caps and Crosses

 

Sizes: ½″ – 48″ (Sch 10S, 40S, 80S, 160, XXS)

 

All items are supplied with EN 10204 3.1 or 3.2 certificates, positive material identification (PMI), and full traceability.

 

Conclusion

 

F51 (UNS S31803/S32205, 1.4462, 2205) remains the workhorse duplex grade for corrosive environments where 316L is insufficient and super duplex is over-specified.

 

For technical datasheets, welding guidelines, or immediate quotations on F51 duplex butt-weld fittings and flanges, please contact our sales team.

 

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